This page was last edited on 12 august 2019, at 19. Uses advised against food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Mtbe is produced in very large quantities over 200,000 barrels per day in the u. This lack of reactivity has led to concerns of the longterm impacts of mtbe in groundwater. Ethers, such as methyl tertbutyl ether, can act as bases. Methanol is purchased but the isobutylene is obtained from a refinery stream.
Mtbe is widely used in global markets as a gasoline oxygenate. Physical and thermodynamic properties of pure chemicals data compilation. If the file has been modified from its original state, some details such as the timestamp may not fully reflect those of the original file. The statewide sampling program confirmed the widespread occurrence of mtbe in heating oil and diesel fuel. Biodegradation of methyl tertbutyl ether mtbe and its.
Mtbe was detected in all samples collected during our sampling program at concentrations. Mtbe is a gasoline additive used to increase octane number that is produced from methanol and isobutylene. High purity mtbe is used as a solvent in the pharmaceutical industry and as a lab solvent. It has weak aesthetic properties, and prolonged exposure to high concentrations may cause signs or symptoms of cns depression. Both cultures were capable of cometabolizing mtbe and the metabolites, tertbutyl formate tbf and tertbutyl alcohol tba. Methyl tertbutyl ether 1634044 hazard summary methyl tertbutyl ether is used as a gasoline additive. Dialkyl ethers are organic compounds containing the dialkyl ether functional group, with the formula ror, where r and r are alkyl groups. Drift studies for the reaction and adsorption of alcohols and isobutylene on acidic resin catalysts and the mechanism of etbe and mtbe synthesis.
Mtbe is manufactured via the chemical reaction of methanol and isobutylene. The other automakers have been very quiet about biodiesel a stance due to change as new diesel vehicles come to the market in the next few years. This page contains pharmcos material safety data sheets. Mysql free tutorial pdf download mysql free tutorial pdf download mysql free tutorial pdf download download. Mtbe methyltertbutyl ether should be considered a potential human carcinogen due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in. Mtbe synthesis from tertbutyl alcohol tba and methanol has been studied using beta zeolites. In the unlikely event of ingestion of mtbe, appropriate lavage procedures should be considered to avoid accidental aspiration of the product. Methyl tertbutyl ether safety data sheet according to federal register vol. They form salts with strong acids and addition complexes with lewis acids. Impacts of ethanol on anaerobic production of tertbutyl. Mtbe is also used as a chemical intermediate to produce high purity isobutylene. Safety data sheet according to federal register vol. This file contains additional information such as exif metadata which may have been added by the digital camera, scanner, or software program used to create or digitize it. Hydrolysis of tertbutyl methyl ether mtbe in dilute.
These files can be easily viewed in adobe acrobat reader. Mtbe m ethyl t ertiary b utyl e ther c5 h 12 o ether oxygenated isopentane fame fatty a cid m ethyl e ster volkswagen, mercedesbenz and ford generally are okay with b5, while chrysler and gm approve b20 for some of their trucks. Download free course a multiple jpeg files to pdf converter online mysql. Increasing the reaction temperature results in an increase of tba conversion with concomittant decrease of mtbe selectivity. Mtbe appears to be degraded readily in the presence of oxygen but is recalcitrant under the anaerobic conditions prevalent in the subsurface, and can be converted into the more toxic compound tertbutanol tba. When clicked the sheets are downloaded to your harddrive in a. In other reactions, which typically involve the breaking of the carbonoxygen bond. Mtbe methyltertbutyl ether should be considered a potential human carcinogen due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in lymphomas, leukemias, and uterine sarcomas in female rats. Although hydrolysis in the presence of strong acids has been recognized as a mechanism for mtbe transformation, it has been discounted as a significant reaction under. The transport of mtbe was simulated using two numerical modeling approaches. Eximpulse services will provide you the latest and relevant market intelligence reports of mtbe import data you can use this mtbe import data for multiple kinds of analysis. Methyl tertbutyl ether mtbe is a mucosal and eye irritant. Articles of methyl tertbutyl ether are included as well.
Methyl tertbutyl ether mtbe is a contaminant of concern to groundwater resources due to its persistence in subsurface environments. The catalytic results are correlated with the surface. The tba conversion decreases with increasing calcination temperature and alkali metal ion exchange of h. Respiratory irritation, dizziness, and disorientation have been reported by some motorists and occupationally exposed workers. Qafac produces 1830 tonnes of mtbe methyl tertiarybutyl ether per day. This is classified as a dangerous good for transport and may be subject to additional shipping charges. Be sure to describe clearly what you are changing and how. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Contains benzene, which can cause blood disease, including anemia. Mtbe is a volatile, flammable, and colorless liquid that is sparingly soluble in water. Mtbe is the common name for a synthetic chemical called methyl tertbutyl ether. It was first introduced as an additive for unleaded gasolines in the 1980s to enhance octane ratings. Exposure may occur by breathing air contaminated with auto exhaust or gasoline fumes while refueling autos. A complex blend of petroleumderived normal and branchedchain.
Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Material safety data sheet gasoline, all grades msds no. Do not allow contact with soil, surface or ground water. Methyl tertbutyl ether mtbe is a flammable liquid with a distinctive, disagreeable odor. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials see section 10 and food and drink.
Contains benzene, which has been classified as a carcinogen by the national toxicology program ntp. Files are available under licenses specified on their description page. Pdf occurrence of mtbe in heating oil and diesel fuel in. Mtbe resource guide european fuel oxygenates association. Download fulltext pdf production of 20,000 mtpd of methyl tertiarybutyl ether mtbe from methanol and butylene by catalytic conversion thesis pdf available october 2016 with 4,545 reads. Search our product to see the coa msds for microbiology products, molecular biology products, animal cell culture, plant tissue culture, chemicals and lab equipments. Mtbe production material balance project you manage a chemical plant within a refinery complex that produces 60,000 tonney of methyl tertiarybutyl ether mtbe. Click on any of the following chemicals below to download the msds sheet. Our msds database is an easy to use, do it yourself tool, and best of all. Box 2650 tulsa, oklahoma 74101 for emergency source information contact. The atsdr toxicological profile succinctly characterizes the toxicologic and adverse health effects information for the hazardous substance described here.
Ethers may react violently with strong oxidizing agents. Adobe acrobat pdf files are supplied to allow use of this product with a wide variety of software, hardware, and operating systems dos, windows, mac, and unix. Methyl tbutyl ether mtbe methyl tbutyl ether mtbe is a clear, colorless organic liquid compound. The biotransformation of methyl tertbutyl ether, ethyl tertbutyl ether etbe, and tertamyl methyl ether tame was studied in humans and in rats after inhalation of 4 and 40 ppm of mtbe, etbe, and tame, respectively, for 4 hours, and the biotransformation of mtbe and tame was studied after ingestion exposure in humans to 5 and 15 mg in water. Mtbemethyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. Mtbe methyl tertiarybutyl ether is a chemical compound that is manufactured by the chemical reaction of methanol and isobutylene. And easy mtbe msds pdf to use mysql uses standard sql mysql compiles on a number of.
It is a flammable liquid made from combinations of chemicals like isobutylene and methanol. Keep away from heat, hot surfaces, sparks, open flames and other. Methyl tertbutyl ether mtbe, also known as tertbutyl methyl ether, is an organic compound. Other pertinent literature is also presented, but is described in less detail than the key studies. Fate of mtbe relative to benzene in a gasoline contaminated aquifer 199398 by james e. Synthesis of methyl tertbutyl ether catalyzed by acidic. All structured data from the file and property namespaces is available under the creative commons cc0 license. It has a distinctive odor that most people find disagreeable. Public health goal for methyl tertiary butyl ether mtbe in drinking water. Methyl tertbutyl ether recommended use laboratory chemicals. We ask that users who download significant portions of the database cite the hmdb. Pdf production of 20,000 mtpd of methyl tertiarybutyl.